The Short Answer
Active PoE is the IEEE-standard kind: before any power flows, the source and the device perform a handshake to agree the voltage and power class, so a device only ever receives what it can take. Passive PoE skips the handshake and applies a fixed voltage to the line regardless of what is connected.
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Negotiation Active negotiates; passive does not.
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Voltage Active ~48 V DC; passive often a fixed 24 V DC.
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Compliance Active follows IEEE 802.3af/at/bt; passive does not.
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Risk Passive power into a device expecting active PoE can damage it.
What We Recommend
For interoperable, protected deployments, specify active, standards-compliant PoE end to end. Passive PoE has a place in closed, known systems, but it should never be mixed with standard PoE equipment without care.
See our guide to industrial Power over Ethernet for the full picture.